To PXE boot the system, make the necessary USB and network connections then power up the system.
As soon as the Dell splash screen is displayed, press the F12 key to bring up the one-time boot selection menu.
Use the arrow keys to highlight “USB NIC(IPV4)” or “USB NIC(IPV6)” depending on network topology in use.
Press enter to boot the system to the network device.
For more details check Dell Latitude E6420 Manual.